Tullio De Mauro's dictionary, free on Internazionale — with frequency labels.
Details
About 160,000 entries, and uniquely useful for learners because De Mauro tags words by frequency band (fondamentale, di alto uso, comune…), so you can see at a glance whether a word is worth learning. Definitions are plainer than Treccani's, which makes it the friendlier first monolingual dictionary. Completely free and ad-supported; the interface is dated and there is no app.